Diphenylsilane CAS 775-12-2 silane chemistry silane manufacturers silane suppliers

Diphenylsilane CAS 775-12-2   silane chemistry   silane manufacturers   silane suppliers

Product Identification

Chemical name: Diphenylsilane

Synonyms: diphenyl-silan; Silane,diphenyl-

CAS No.: 775-12-2

Molecular formula: C12H12Si

Molecular weight: 184.31

Boiling point: 95-97 ℃ @ 13 mmHg

Density: 0.993g/mL @ 25°C

Refractive index: 1.579

Specification

Appearance: Colorless transparent liquid

Purity: 98.00%min by GC

Package

Regular Packing: N.W 20kg/iron drum lined with plastic

Sample Packing: 0.1kg-1kg plastic bottle or under request

Transportation Information

Classification: Non-dangerous goods  

   

HS Code: 2931900090

Application

NHC-catalyzed dehydrogenative self-coupling of diphenylsilane: A facile synthesis of octaphenylcyclotetra(siloxane)

A unique application of the CuIPr N-heterocyclic carbene (NHC) to the dehydrogenative self-coupling of diphenylsilane has been discovered. This transformation is carried out open to air at room temperature, yielding octaphenylcyclotetra(siloxane) quantitatively in 1 h. This preparation constitutes a significant improvement over existing methods for the preparation of this compound and demonstrates a novel mode of reactivity for CuIPr. The diphenylsilanone tetramer is the precursor to a number of industrially significant polymers.

Reference: Albright, Abigail; Gawley, Robert E. [Tetrahedron Letters, 2011, vol. 52, # 46, p. 6130 - 6132]

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